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    Как-то одна мадам пригласила к для себя на пару чашек чаю, но предупредила, что дома у неё необыкновенный любимец. Ну боюсь я из до усрачки. Открывает она означает дверь, а там таковой топот, как шлепками по кафелю. Включает свет, а на меня глядит здоровая игуана! Она мне тоже лапу протянула. Ну а далее всё, норм пошло. Российский протягивает 1 евро: — Я так и знал, что за один евро ты вспомнишь русский!!

    Ровно 3 месяца назад не стало моей супруги. И я в порыве отчаяния запилил пост с вопросцем как огласить о этом детям. Я получил множество советов и большущее количество слов поддержки. На данный момент не стало легче. Да и вряд ли станет. Но мы стараемся управляться и жить далее. Мы друг друга отвлекаем от грустных мыслей и веселим. Мне кажется не будь у меня малышей я бы уже сошел с мозга Самое тяжелое оказалось это "чек поинты": здесь мы гуляли, здесь кофе пили, здесь я предложение сделал, это ее возлюбленная песня и т.

    И в такие моменты бывают срывы, слезы Но кажется ежели время от времени не давать волю чувствам можно просто взорваться. Хорошо о грустном, я к чему это Ребят, спасибо всем огромное! Вот те ваши буковкы в моем телефоне - это так ценно.

    Это неописуемо приятно, что так много незнакомых мне людей меня поддержали в томную минутку. Мы здесь стресс снимаем выпечкой с детками. Ловите вкусняшки. Стоит в два раза дешевле аналога. Тридцатое декабря, вечер. Пробежался по магазину, отошёл в сторону, достал листочек, где супруга написала, чего же перед НГ нужно докупить.

    Проверился, взял всё по списку. Рядом топчется и не отходит какой то мужчина. Поворачиваюсь к нему. Я собственный на работе перечитывал, да на столе и запамятовал. Спасибо, друг, с наступающим тебя и твою жену! Вот таковая милота была в нашей мастерской. Этот кроха уже издавна бы был на мусорке, но ситуация поменялась. Его выручил внимательный член семьи, ведь этот стул помнит детство их семьи.

    Беглый осмотр показал, необходимо будет попотеть над разборкой без поломок. Все детали были наглухо закреплены тонкими шкантиками шпажками насквозь. Разобравшись со шкантами перешёл к разборке. Опосля к зачистке от старенького покрытия и очистке всех соединений от клея. Дальше перешёл к изготовлению отсутствующей детальки.

    Сделал потеряшку из массива бука. Заделал все отверстия шпаклёвкой по дереву. Оставил всё это дело на день просушить, опосля приступил к шлифовке. Опосля финишной примерки с конечной клейкой. Передал его для тонировке в руки собственного отца, я же перешёл к изготовлению сидушки. Вырезал её из фанеры в 4 мм, наполнитель для сидухи употреблял 1,5 см плотного поролона.

    Через день покрыл первыми слоем грунта. На последующей утро нанес 2-ой слой и лишь на 3-ий день покрыл лаком. Люди с Украины не соображают зеркальности ситуации. Попробую объяснить главную сущность. Поймите уже одну сущность. Вот как вы не могли воздействовать на ситуацию все 8 лет - так и мы не можем воздействовать на неё сейчас. И мы, как и вы, не виноваты ни в чём. А ежели виноваты мы - то виноваты и вы, и получаете по заслугам за ЛДНР. Спасибо силовикам и всем неравнодушным.

    Я желал бы осторожно напомнить Пикабушникам и общественности, что 4 месяца назад студента, который помочился на щит с портретом ветерана ВОВ упекли на 4 года , и извинениями отделаться у него не вышло. Давайте заставим работать закон во все стороны? И у зрителей возникает резонный вопросец, как и у меня. Схуяли все такие незапятнанные и ухоженные? У меня брат просидел в подвале 21 день в Мариуполе, вылезали естественно наверх, поесть приготовить, вылазки за пищей и водой.

    Топили снег чтобы промыть хоть лицо и простейшую гигиену произвести. Так он когда выехали, кума просил состричь хоть тупыми ножницами волосы на голове, ибо просто хер вымоешь. Да, я понимаю что там у их и техвода есть, но в ледяной техводе дохуя не намоешь. Я уже молчу про ухоженные бороды и чистую кожу. Короче ежели уж снимаете хуету, хоть подходите творчески.

    Хорошего времени суток, общество. Мне Начал курить спайс в 17 лет, так раз когда он лишь возник и тогда просто баловались и курили чрезвычайно изредка и было это что-то особенно и жутко прикольно. Почему начал курить? Пропаганда марихуаны в репе. А я так раз слушал реп южноамериканский и российский.

    Но никак не мог отыскать марихуану, а здесь для тебя в городке начали продавать аж в магазинах "альтернативу марихуаны" и чрезвычайно дешево р за 1 гр наркотика, которого хватало на месяц. И так со временем и медлительно, но правильно начали с друзьями наращивать дозы и частоту потребления.

    Спустя год дошло, что в недельку был один день "сухой" без потребления , а спустя еще пол года уже в месяц были пару дней без наркотика, все другие дни были в "дурмане". Но, понимаете, это не мешало жизни. У меня была женщина, машинка, учеба в институте. Просто курили в свободное время. В полностью хоть какое свободное время.

    Перед институтом, на большой перемене, опосля института. Просыпаешься - идешь первым делом курить сигарету и "подкуриваться" спайсом. Перед сном ты подкуриваешься и ложишься. Как и говорил - курили везде и постоянно, не считая в тех вариантах где откровенно это было нельзя делать.

    Хотя и в таковых местах тоже умудрялись. Курили с друзьями прям на лекции в поточной аудитории. В торговых центрах, в кинозале. Лишь в театре, наверняка, не курили В итоге дошло до того, что тебя уже не прёт спайс, а просто куришь, чтоб поддерживало постоянно. Понимание того, что ты "под-убитый". Ну и как со всеми наркотиками бывает, ежели злоупотреблять и наглеть - то будет лишь ужаснее. Машинку из-за этого растерял, разругался сильно с родителями, так как не однократно палился.

    Но, в прочем с женщиной расстались не из-за спайса. Позже мысли с друзьями о том, чтоб начать торговать данной для нас хернёй, а не глупо растрачивать средства. А, кстати, о деньгах. Представляете, в моей компании с кем курил постоянно.

    Друзья никто не работал, но каждый день мы находили по рублей. При этом не занимая огромных сумм и постоянно в итоге отдавали быстро. У нас была схема еще одна: мы "мутили" за остальных за часть веса. There have also been reports of a strong compulsion to re-dose, withdrawal symptoms , and persistent cravings. The Centers for Disease Control and Prevention CDC found that the number of deaths from synthetic cannabinoid use tripled between and Synthetic cannabinoids reagent testing kits recently became economical.

    It is often difficult to determine what is in these products without reagent testing because masking agents , such as tocopherol or vitamin E acetate that causes vaping-associated pulmonary injury , eugenol , and fatty acids , are added to confound identification. Just as the synthetic cannabinoid s used differ between each synthetic cannabinoid product sold, so do the other contents of the counterfeit product.

    Synthetic cannabinoids appear in many CBD brands in products such as gummy bears, and vape cartridges. Most blends consist of synthetic cannabinoids sprayed onto inert vegetable matter, but some contain other psychoactive substances , including psychoactive herbs, e. Some synthetic cannabinoids products have also been found to contain synthetic opioids. One of the most common non-cannabinoid ingredients in these products is oleamide , a fatty acid derivative that acts similarly to a cannabinoid and has hypnotic properties.

    Packages of synthetic cannabinoid products can claim to contain a wide array of plants. However, oftentimes, none of the listed ingredients have been detectable. Many of the early synthetic cannabinoids that were synthesized for use in research were named after either the scientist who first synthesized them or the institution or company where they originated.

    Some of the names of synthetic cannabinoids synthesized for recreational use were given names to help market the products. Now many synthetic cannabinoids are assigned names derived from their four main structural components, core, tail, linker, and linked group, where the name is formatted as LinkedGroup-TailCoreLinker. Use of the term "synthetic marijuana" to describe products containing synthetic cannabinoids is controversial and, according to Lewis Nelson, a medical toxicologist at the NYU School of Medicine, a mistake.

    Nelson claims that relative to marijuana , products containing synthetic cannabinoids "are really quite different, and the effects are much more unpredictable. Nearly "herbal incense" blends exist. According to the Psychonaut Web Mapping Research Project, synthetic cannabinoids, sold under the brand name Spice, were first released in by the now-dormant company the Psyche Deli in London.

    In , the brand gained popularity. Because of these controversies, [50] and in particular the difficulty to distinguish natural cannabinoids obtained in laboratory for example, CBD or synthetic THC from artificial novel synthetic cannabinoid analog compounds not present in nature like nabilone, Spice, the HU, JWH series, etc. Synthetic cannabinoids were made for cannabinoid research focusing on tetrahydrocannabinol THC , cannabinoid receptors , and the endocannabinoids that activate them in the body.

    Synthetic cannabinoids were needed partly due to legal restrictions on natural cannabinoids , which make them difficult to obtain for research. Tritium -labelled cannabinoids such as CP, were instrumental in discovering the cannabinoid receptors in the early s. Some early synthetic cannabinoids were also used clinically. Nabilone , a first generation synthetic THC analog, has been used as an antiemetic to combat vomiting and nausea since Synthetic THC marinol, dronabinol has been used as an antiemetic since , and an appetite stimulant since , [53] although synthetic THC is often not listed among the "synthetic cannabinoids" but as a "synthetic phytocannabinoid.

    In the early s, synthetic cannabinoids began to be used for recreational drug use in an attempt to get similar effects to cannabis. Because synthetic cannabinoid molecular structures differ from THC and other illegal cannabinoids, synthetic cannabinoids were not technically illegal. Since the discovery of the use of synthetic cannabinoids for recreational use in , some synthetic cannabinoids have been made illegal , but new analogs are continually synthesized to avoid the restrictions.

    Synthetic cannabinoids have also been used recreationally because they are inexpensive and are typically not revealed by the standard marijuana drug tests. Unlike nabilone , the synthetic cannabinoids found being used for recreational use did not have any documented therapeutic effects. Because they activate the cannabinoid CB1 and CB2 receptors, many of the effects of synthetic cannabinoids are similar to those of THC.

    These are achieved at lower doses, because many synthetic cannabinoids are more potent than marijuana, and users are often unaware of exactly what they are getting and how potent it is. Some of the negative effects of 5F-AKB reported by users included palpitations , paranoia , intense anxiety, and a taste like burned plastic. Researchers have pointed out a few ways that synthetic cannabinoids differ from marijuana, and therefore may be more dangerous.

    First, they often have greater intrinsic activity. Many of the synthetic cannabinoids are full agonists of the cannabinoids receptors , CB 1 and CB 2 , compared to THC , which is only a partial agonist. Some may work on NMDA glutamate receptors. Phase 1 metabolism of JWH results in at least nine monohydroxylated metabolites , three of which have been shown to be full agonists of the CB 1 receptors , compared to the metabolism of THC , which only results in one psychoactive monohydroxylated metabolite.

    The metabolite N- 3-hydroxypentyl JWH was found to have toxic effects that its parent compound does not. No official studies have been conducted on the effects of synthetic cannabinoids on humans as is often the case with illegal and potentially toxic compounds ; [71] however, user reports and the effects experienced by patients seeking medical care after taking synthetic cannabinoids have been published.

    Each of the many different synthetic cannabinoids can have different effects at different dosages. The CDC described synthetic cannabinoid overdoses between and and of drug overdose patients who reported synthetic cannabinoid as the sole agent, Four postmortem cases linked to the synthetic cannabinoids 5F-PB have been reviewed. The postmortem blood specimens contained a range of 1. Three of the four cases were sudden episodes and the symptoms leading to death included acute shortness of breath; vasocongestion in the liver, spleen, and kidneys; bilateral pulmonary edema ; dead inflamed tissue necrotizing granulomatous inflammation ; and congestion of most internal organs.

    The fourth case presented to the hospital with severe problems that deteriorated over the course of a day, ending with circulatory , respiratory , central nervous system , and renal failure. There have been reports of a strong compulsion to re-dose, withdrawal symptoms , and persistent cravings lasting up to a week after taking synthetic cannabinoids, indicating that synthetic cannabinoids may be more addictive than marijuana.

    Studies are currently available that suggest an association between synthetic cannabinoids and psychosis. In contrast to most other recreational drugs , the dramatic psychotic state induced by use of synthetic cannabinoids has been reported, in multiple cases, to persist for several weeks, and in one case for seven months, after complete cessation of drug use. There are five major categories for synthetic cannabinoids: classical cannabinoids, non-classical cannabinoids, hybrid cannabinoids, aminoalkylindoles , and eicosanoids.

    Classical cannabinoids are analogs of THC that are based on a dibenzopyran ring. They were developed starting in the s, following the isolation of THC, [49] and were originally the only cannabinoids synthesized. It was discovered in herbal incense products by the U. Customs and Border Protection in January ; however, classical cannabinoids are not often seen in synthetic cannabinoid blends for recreational use , likely because they are difficult to synthesize.

    Non-classical cannabinoids include cyclohexylphenols CP , which were first synthesized in the late s to s by Pfizer as potential analgesics. CP,C8 is made by extending the dimethylheptyl side chain of CP, to a dimethyloctyl side chain. It was discovered by forensic scientists in an herbal blend known as "Spice" in , along with JWH , an aminoalkylindole.

    Hybrid cannabinoids have a combination of classical and non-classical cannabinoid structural features. Aminoalkylindoles are considered to be the most common synthetic cannabinoids found in synthetic cannabinoid blends, likely due to the fact that these molecules are easier to synthesize than classical and non-classical cannabinoids. Eicosanoid synthetic cannabinoids are analogs of endocannabinoids , such as anandamide. Endocannabinoids are cannabinoids naturally occurring in the body.

    One of the best known synthetic analogs of anandamide is methanandamide. The synthetic cannabinoids that have emerged recently have even greater structural diversity, possibly to subvert legal regulations on earlier generations of synthetic cannabinoids. There are a few different structural classifications of synthetic cannabinoids that include many of the new structures, some of which are shown in table one. PB and 5F-PB were the first synthetic cannabinoids to include a quinoline substructure and an ester linkage.

    These compounds are thought to have been synthesized with the intention of making a synthetic cannabinoid prodrug , which might improve absorption and confound detection. Ester bonds are easily biodegradable through spontaneous or endogenous , nonspecific esterase hydrolysis, which has been commonly used in medicinal chemistry to make ester prodrugs.

    The reason for the change to the quinolone substructure is unknown, but it may have been found to be a suitable replacement for the naphthoyl moiety that is currently regulated by US scheduling laws. Most are lipid-soluble , non-polar , small molecules usually carbon atoms that are fairly volatile , making them "smokable," like THC. It has been found that this chain of carbons is required for optimal psychotropic activity from binding CB 1 receptors.

    Due to the greater potency , the standard doses of many synthetic cannabinoids may be less than 1 mg. Most classical, non-classical, and hybrid synthetic cannabinoids have stereospecificity one stereoisomer is usually much more potent than the other s.

    Recently there has been an increase in the emergence of terminally fluorinated synthetic cannabinoids, such as 5F-PB fluorinated version of PB and XLR fluorinated version of UR On October 20, , the Louisiana State University football program announced that it had suspended three players, including star cornerback Tyrann Mathieu , who tested positive for synthetic cannabinoids. In the autumn of , more than two-thousand Spice consumers in Russia sought medical attention, one-thousand were admitted to hospitals, and 40 people died.

    On July 12, , 33 people were intoxicated by an herbal "incense" product called "AK 24 Karat Gold," [] and dozens overdosed , in Brooklyn. Since March , Illinois, Wisconsin, Maryland, and 8 other states in the United States have had an outbreak of severe bleeding caused by a synthetic cannabinoid contaminated with brodifacoum , a rat poison that causes bleeding. Illinois was hit the hardest [] and on April 5, , the CDC issued a Clinical Action alert to health care providers across the United States advising of 89 confirmed cases of "serious unexplained bleeding" in Illinois.

    The cases are still being studied; however, 63 of the patients reported synthetic cannabinoid use, and laboratory analysis confirmed brodifacoum was present in at least 18 patients. In August , there were almost one hundred overdose cases reported over two days in New Haven, Connecticut from a bad batch of K2.

    The synthetic cannabinoid was believed to have been mixed with fentanyl , although no fentanyl was identified in samples of the drug tested by the DEA. Some of the people are in critical condition in the Intensive Care Unit. From September 21—22, , almost 50 people overdosed and two people died in the Kensington area of Philadelphia. Tests are still in progress, but officials believe the cause to be a combination of heroin or fentanyl and a synthetic cannabinoid.

    The Department of Public Health released that they believe " 5F-ADB was the primary cause of the cluster of patients with these adverse drug reactions. Synthetic cannabinoids have been speculated to be involved in vaping-associated pulmonary injury VAPI. The Austrian Ministry of Health announced on December 18, , that Spice would be controlled under Paragraph 78 of their drug law on the grounds that it contains an active substance that affects the functions of the body, and the legality of JWH is under review.

    From June , JWH, along with a variety of other designer drugs, has been illegal. On April 3, , parliament made selling of the temporarily banned substances a criminal offense. JWH and many of the herbs mentioned on the ingredient lists of Spice and similar preparations were made illegal in May The bill was passed by Polish Sejm [] [] and Polish Senat [] and was signed by the President. Spice was made illegal in Romania on February 15, As on 12 September Spice was made legal for personal use.

    On April 9, , the Chief Medical Officer of the Russian Federation issued a resolution on reinforcing control over the sales of smoking blends. These substances have been found to have "psychotropic, narcotic effects, contain poisonous components and represent potential threat for humans". The resolution does not mention JWH or other synthetic cannabinoids.

    About new psychoactive substances were added to the list from to The drugmakers avoided all the bans by making slight changes to the drugs. In the autumn of , more than two-thousand Spice consumers in Russia sought medical attention, one-thousand were admitted to hospitals, and 40 people died [] On October 30, , President Vladimir Putin brought in a bill that increased the penalty for selling or consuming smoking blends from a fine to up to eight years in prison.

    Spice is legal in Slovakia. The National Anti-Drug Unit is considering adding it to the list of controlled substances. Spice is unregulated in Spain. For this reason, Spice is available in grow shop stores or cannabis related stores, and it can be bought and shipped online without any legal impediment from those kind of stores.

    The bill was accepted on July 30, , and was put in effect on September 15, Spice has been banned in Switzerland. Spice, which is colloquially called bonzai in Turkey, was added to the list of drugs and psychotropic substances on July 1, , by the law numbered as — B. February 13, and the Official Gazette No. The UK saw three generations of synthetic cannabinoids within five years where the second and third generations emerged in response to amendments to the Misuse of Drugs Act, , Order [] and Order , [] which classified many first and second generation synthetic cannabinoids as Class B drugs.

    There were two additional amendments in and , which included in the analog controls many of the most popular synthetic cannabinoids circulating at the time. Spice is not specifically prohibited in Canada, but synthetic cannabis mimics are listed as a schedule II drug. Rozga shot himself in the head with a family-owned hunting rifle in an apparent suicide on June 6, The nature of his death and reports from numerous family members, led investigators to suspect that Rozga was under the influence of a mind-altering substance when he died.

    The death of Rozga influenced political lobbying against K2, and other legal synthetic drugs such as bath salts. It was passed by the United States Congress in June It banned synthetic compounds commonly found in synthetic marijuana, placing them under Schedule I of the Controlled Substances Act. Prior to that, some synthetic cannabis compounds HU were scheduled in the US under federal law, while others JWH were temporarily scheduled until final determination of their status could be made.

    Adverse health effects associated with its use include seizures, hallucinations, paranoid behavior, agitation, anxiety, nausea, vomiting, racing heartbeat, and elevated blood pressure. Several states independently passed acts making it illegal under state law, including Kansas in March , [] Georgia and Alabama in May , [] [] Tennessee and Missouri in July , [] [] Louisiana in August , [ citation needed ] Mississippi in September , [ citation needed ] and Iowa.

    Dennis Daugaard on February 23, and which took immediate effect under an emergency clause of the state constitution. Following cases in Japan involving the use of synthetic cannabinoids by navy, army and marine corps personnel, they were officially banned. Usage among 8th, 10th, and 12th graders has been decreasing since , while use of botanical marijuana has remained stable. The Chilean Ministry of Health on April 24, , declared the sale of synthetic cannabis mimics to be illegal.

    Tembakau Gorilla Gorilla Tobacco , a catch-all term for synthetic cannabinoids blended in tobacco products, were listed as Class I Narcotics with no therapeutic use in The United Arab Emirates had stated that Spice is an illegal substance and possession or intent to sell is a jailable offense. On June 17, , the Western Australian government banned all of the synthetic cannabinoids found in already existing products, including brands such as Kronic, Kalma, Voodoo, Kaos, and Mango Kush.

    Western Australia was the first state in Australia to prohibit the sale of certain synthetic cannabinoids. Spice is illegal in New Zealand, it is classified as a Class C controlled drug. In two brands, the benzodiazepine anxiolytic drug phenazepam was also found, which is classified as a prescription medicine in New Zealand, and these brands were ordered to be removed from the market by emergency recall.

    From Wikipedia, the free encyclopedia. Designer drugs. See also: Comparison of phytocannabinoids. United Nations Office on Drugs and Crime. Retrieved Tetrahedron: Asymmetry. ISSN PMC PMID Drug Science, Policy and Law. S2CID Huffington Post. Clinical Pharmacology and Therapeutics. August ACS Chemical Neuroscience.

    Analytical Chemistry. Department of Health and Human Services. Journal of Medical Toxicology. June 12, United States Food and Drug Administration. July 19, Retrieved 14 June The Observer. The Independent. ITV News. Frontiers in Behavioral Neuroscience. Forensic Toxicology. The American Journal of Nursing. Forensic Science International. Legal Medicine.

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